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- W2022270655 abstract "[Bu4N]VO3 or a combination of vanadium complexes with chloride salts are attractive co-catalysts for oxidation reactions of organic compounds with dioxygen catalysed by N-hydroxyphthalimide. The role of the chloride additive relates to the formation of more labile six-coordinate vanadium complexes. The same effect is also observed with amines. Two catalytic systems based on NHPI/VO(acac)2 with LiCl or [Bu4N]Cl and NHPI/[Bu4N]VO3 are most effective in oxidation reactions of primary and secondary alcohols, but oxidation of alkylaromatics proceeds with conversion rates of from 14.4% in the case of toluene to 67.0% in the case of ethylbenzene and with different selectivities, dependent on the structure of the substrate." @default.
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- W2022270655 date "2007-01-01" @default.
- W2022270655 modified "2023-10-18" @default.
- W2022270655 title "Aerobic oxidation of alcohols and alkylaromatics with dioxygen catalysed by N-hydroxyphthalimide with vanadium co-catalysts" @default.
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- W2022270655 doi "https://doi.org/10.1039/b702443f" @default.
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