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- W2022271063 abstract "Abstract The oxygen-stoichiometric spinel Li[Ni0.5Mn1.5]O4 is an insulator with ordered Ni(II) and Mn(IV). Although it delivers 4.7 V versus Li, the ordered phase gives poor performance as the cathode of a Li-ion battery. Here we demonstrate control of the degree of cation order by adjusting the oxygen stoichiometry with thermal history of the synthesis rather than by doping 2M(III) for Ni(II) + Mn(IV) (M = Cr, Mn, Fe, Co, Al, Ga). We report retention of capacity near 100 mAh g−1 at room temperature at 10C/10C charge/discharge rate with little capacity fade; at 55 °C, a capacity fade occurs as a result of reaction with the electrolyte, but it is reduced to a level comparable to that obtained by doping." @default.
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- W2022271063 date "2013-12-01" @default.
- W2022271063 modified "2023-09-23" @default.
- W2022271063 title "Influence of thermal history on the electrochemical properties of Li[Ni 0.5 Mn 1.5 ]O 4" @default.
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- W2022271063 doi "https://doi.org/10.1016/j.jpowsour.2013.05.189" @default.
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