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- W2022271628 abstract "Two series of complexes which contain planar chirality have been examined as intermediates for the synthesis of tridachione. Alkylation of tricarbonyl(η5-2-methoxy-3,5-dimethylcyclohexadienyl)iron(1+) hexafluorophosphate(1–) with trimethylsilyl cyanide and reaction of the nitrile product with ethyl-lithium afforded an acyl-substituted intermediate for the synthesis of tridachione. Complexation of 1-methoxy-2,4-dimethylbenzene by Mn(CO)3+ gave a complex that was alkylated by vinyl Grignard reagents at the correct position to introduce the 1-methylpropenyl group in tridachione. Methylmagnesium bromide gave predominantly an unexpected regioisomer. These products were converted into Mn(CO)2NO+ dienyl complexes. The influence of the use of planar chirality on the design of synthetic strategies is discussed." @default.
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- W2022271628 date "1988-01-01" @default.
- W2022271628 modified "2023-10-16" @default.
- W2022271628 title "Transition–metal mediated asymmetric synthesis. Part 6. Organometallic approaches to the enantiomer synthesis of tridachione: a role for planar chirality in synthesis design" @default.
- W2022271628 doi "https://doi.org/10.1039/p19880002069" @default.
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