FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022273032> ?p ?o ?g. }

• W2022273032 endingPage "4569" @default.
• W2022273032 startingPage "4569" @default.
• W2022273032 abstract "The gas phase structure of deprotonated cysteine (Cys-H(+))(-) has recently gained attention because of its counterintuitive calculated minimum energy structure in which it appears that deprotonation occurs at the -SH moiety rather than at the nominally more acidic carboxylic acid group. Because previous experimental efforts have not yielded to a consensus regarding the structure of the anion, we report the cryogenic ion vibrational predissociation (CIVP) spectra of its cryogenically cooled H/D isotopologues in an effort to clarify the situation. The unexpected isotope dependence of key features in the spectrum and the similarity of the band pattern to that displayed by the intramolecular H-bonded linkage in a deprotonated diacid (HCO2(CH2)10CO2(-)) indicate that the dominant form of the anion occurs with a strongly shared proton between the thiolate (-S(-)) and carboxylate (-CO2(-)) groups. An interesting aspect of this (-S(-)···H(+)···(-)O2C-) linkage is that, although the global minimum places the shared proton closer to the oxygen atom, the soft potential energy curve calculated for displacement of the bridging proton would likely support sufficient zero-point motion both to blur the distinction between thiolate- and carboxylate-based structures and to account for the unusual isotope effects." @default.
• W2022273032 created "2016-06-24" @default.
• W2022273032 creator A5022283101 @default.
• W2022273032 creator A5031623363 @default.
• W2022273032 creator A5041611668 @default.
• W2022273032 date "2014-01-01" @default.
• W2022273032 modified "2023-09-25" @default.
• W2022273032 title "On the character of the cyclic ionic H-bond in cryogenically cooled deprotonated cysteine" @default.
• W2022273032 cites W1982770456 @default.
• W2022273032 cites W1987830612 @default.
• W2022273032 cites W2001058505 @default.
• W2022273032 cites W2012047516 @default.
• W2022273032 cites W2013184597 @default.
• W2022273032 cites W2015477832 @default.
• W2022273032 cites W2016770808 @default.
• W2022273032 cites W2025077754 @default.
• W2022273032 cites W2025262898 @default.
• W2022273032 cites W2038471251 @default.
• W2022273032 cites W2040390474 @default.
• W2022273032 cites W2045639284 @default.
• W2022273032 cites W2061161134 @default.
• W2022273032 cites W2066429539 @default.
• W2022273032 cites W2067668869 @default.
• W2022273032 cites W2068649704 @default.
• W2022273032 cites W2071753502 @default.
• W2022273032 cites W2072352968 @default.
• W2022273032 cites W2080354700 @default.
• W2022273032 cites W2084067334 @default.
• W2022273032 cites W2094680016 @default.
• W2022273032 cites W2112581429 @default.
• W2022273032 cites W2129514698 @default.
• W2022273032 cites W2162293678 @default.
• W2022273032 cites W2312833971 @default.
• W2022273032 cites W2418222258 @default.
• W2022273032 cites W2952663906 @default.
• W2022273032 doi "https://doi.org/10.1039/c3cp54117g" @default.
• W2022273032 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24457297" @default.
• W2022273032 hasPublicationYear "2014" @default.
• W2022273032 type Work @default.
• W2022273032 sameAs 2022273032 @default.
• W2022273032 citedByCount "17" @default.
• W2022273032 countsByYear W20222730322014 @default.
• W2022273032 countsByYear W20222730322015 @default.
• W2022273032 countsByYear W20222730322016 @default.
• W2022273032 countsByYear W20222730322017 @default.
• W2022273032 countsByYear W20222730322018 @default.
• W2022273032 countsByYear W20222730322019 @default.
• W2022273032 countsByYear W20222730322020 @default.
• W2022273032 countsByYear W20222730322021 @default.
• W2022273032 countsByYear W20222730322022 @default.
• W2022273032 countsByYear W20222730322023 @default.
• W2022273032 crossrefType "journal-article" @default.
• W2022273032 hasAuthorship W2022273032A5022283101 @default.
• W2022273032 hasAuthorship W2022273032A5031623363 @default.
• W2022273032 hasAuthorship W2022273032A5041611668 @default.
• W2022273032 hasConcept C118629725 @default.
• W2022273032 hasConcept C121332964 @default.
• W2022273032 hasConcept C145148216 @default.
• W2022273032 hasConcept C147597530 @default.
• W2022273032 hasConcept C178790620 @default.
• W2022273032 hasConcept C184779094 @default.
• W2022273032 hasConcept C185592680 @default.
• W2022273032 hasConcept C2182769 @default.
• W2022273032 hasConcept C2778074193 @default.
• W2022273032 hasConcept C54516573 @default.
• W2022273032 hasConcept C58364064 @default.
• W2022273032 hasConcept C62520636 @default.
• W2022273032 hasConcept C69928629 @default.
• W2022273032 hasConcept C71240020 @default.
• W2022273032 hasConcept C75079739 @default.
• W2022273032 hasConcept C75473681 @default.
• W2022273032 hasConcept C8010536 @default.
• W2022273032 hasConceptScore W2022273032C118629725 @default.
• W2022273032 hasConceptScore W2022273032C121332964 @default.
• W2022273032 hasConceptScore W2022273032C145148216 @default.
• W2022273032 hasConceptScore W2022273032C147597530 @default.
• W2022273032 hasConceptScore W2022273032C178790620 @default.
• W2022273032 hasConceptScore W2022273032C184779094 @default.
• W2022273032 hasConceptScore W2022273032C185592680 @default.
• W2022273032 hasConceptScore W2022273032C2182769 @default.
• W2022273032 hasConceptScore W2022273032C2778074193 @default.
• W2022273032 hasConceptScore W2022273032C54516573 @default.
• W2022273032 hasConceptScore W2022273032C58364064 @default.
• W2022273032 hasConceptScore W2022273032C62520636 @default.
• W2022273032 hasConceptScore W2022273032C69928629 @default.
• W2022273032 hasConceptScore W2022273032C71240020 @default.
• W2022273032 hasConceptScore W2022273032C75079739 @default.
• W2022273032 hasConceptScore W2022273032C75473681 @default.
• W2022273032 hasConceptScore W2022273032C8010536 @default.
• W2022273032 hasIssue "10" @default.
• W2022273032 hasLocation W20222730321 @default.
• W2022273032 hasLocation W20222730322 @default.
• W2022273032 hasOpenAccess W2022273032 @default.
• W2022273032 hasPrimaryLocation W20222730321 @default.
• W2022273032 hasRelatedWork W1994674083 @default.
• W2022273032 hasRelatedWork W2038903849 @default.
• W2022273032 hasRelatedWork W2044287130 @default.
• W2022273032 hasRelatedWork W2069483437 @default.

• next