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- W2022273463 abstract "Optimized consecutive regioselective dimetallation and carboxylation of 4,4,6,6-tetramethyl-4H,6H-pyrrolo[1,2-a][4,1]benzoxazepine provided the corresponding dicarboxylic acid as a new, structurally rigid member of the atropisomeric 1-arylpyrrole family. Resolution of the new racemate was accomplished with several chiral bases and the absolute configurations of the pure enantiomers were determined by the combined application of ECD spectroscopy and quantum chemical calculations." @default.
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- W2022273463 date "2010-12-01" @default.
- W2022273463 modified "2023-10-10" @default.
- W2022273463 title "Synthesis and resolution of 4,4,6,6-tetramethyl-4H,6H-pyrrolo[1,2-a][4,1]benzoxazepine-1,10-dicarboxylic acid" @default.
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- W2022273463 doi "https://doi.org/10.1016/j.tetasy.2010.12.005" @default.
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