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- W2022275310 abstract "Abstract Enantiomerically pure L- erythro - and L- threo -4-fluoroglutamic acids 1a and 1b were conveniently prepared. The key steps in this synthesis relied upon separation of diastereomers of N -chloroacetyl-4-fluoroglutamic acid 5-methyl ester 7 by recrystallization and enzymatic resolution of enantiomers of the resulting 7(a+c) and 7(b+d) by aminoacylase. Protection of the γ-carboxyl group as a methyl ester was found to be crucial for this enzymatic reaction." @default.
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- W2022275310 date "1996-12-01" @default.
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- W2022275310 title "Practical synthesis of L-erythro- and L-threo-4-fluoroglutamic acids using aminoacylase" @default.
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- W2022275310 doi "https://doi.org/10.1016/s0957-4166(96)00462-4" @default.
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