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- W2022276904 abstract "A series of mononuclear iron(III) complexes as functionaland structural model compounds for intradiol cleaving catechol dioxygenaseswere synthesized. For all model compounds the iron(III) cores arein a distorted octahedral environment derived from tripodal tetradentate N4-donorligands and a catechol. Model complexes for enzyme–substrate adductswere characterized by spectroscopic and electrochemical methods, and in fourcases by single-crystal X-ray crystallography. The systematic variation ofone ligand arm in the structurally characterized complexes yields a differentsteric shielding of the iron(III) center, significantly influencingthe bonding of the catechol substrate and the subsequent reaction with dioxygen.The spectroscopic features and catechol cleaving activities of in situgenerated complexes with the above ligands were probed. All complexes arehighly reactive towards intradiol cleavage of various catechols in the presenceof air. The catechol 1,2-dioxygenase reaction depends on the redox potentialof both the iron(III) complex and the catechol derivative as wellas the steric demand of the tripodal ligand. Some complexes show high catalyticactivities with yields up to 84% with respect to aerial cleavage of catechols." @default.
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- W2022276904 date "2001-01-01" @default.
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- W2022276904 title "The systematic influence of tripodal ligands on the catechol cleaving activity of iron(III) containing model compounds for catechol 1,2-dioxygenases †" @default.
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