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- W2022282923 abstract "Abstract Functionalized alkynes are oxidized to the corresponding α-diketones with catalytic RuO4 and NaIO4. Treatment of these diones with metal acetylenides then gives mixtures of erythro- and threo-1,5-hexadiyne-3,4-diols with good erythro-selectivity. Reaction of the erythro-diols with thiophosgene in the presence of n-BuLi or KH as base results in the formation of the corresponding cyclic thionocarbonates in moderate to good yields. Reaction of the cyclic thionocarbonates with 1,3-dimethyl-2-phenyl-1,3,2-diazaphospholidine at 40 oC results in the formation of enediynes substituted at the 3- and 4-positions. As anticipated fom the mechanism of the pericyclic syn-elimination, the erythro-thionocarbonates provide pure Z-enediynes." @default.
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- W2022282923 date "1999-02-01" @default.
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- W2022282923 title "Synthesis Of Fully-Substituted Enediynes by the Corey-Winter Reaction" @default.
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- W2022282923 doi "https://doi.org/10.1080/00397919908085778" @default.
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