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- W2022282932 abstract "The unit cell dimensions of binary and ternary phases with the ThMn12 structure (tetragonal MN12) are analysed in relation to the diameter of the M component and are shown to depend on the N(1)-N(1), N(1)-N(3) or M-N(2) interatomic contacts, or on averages of their effects in simple proportion. The observations are consistent with a lemma, previously advanced, which specified how more than one set of interatomic contacts can combine in controlling unit cell dimensions. The mechanism found here is in interesting contrast with that previously found for tetrahedrally close-packed structures of the A15, MgCu2 and σ phase types, where the interpenetrating coordination polyhedra impose conditions of a cooperative nature, in so far as the effects due to one set of interatomic contacts are not independent of the other interatomic contacts in the polyhedra." @default.
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- W2022282932 date "1984-01-01" @default.
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- W2022282932 title "Analysis of the unit cell dimensions of phases with the ThMn12 structure: I" @default.
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