FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022285477> ?p ?o ?g. }

• W2022285477 endingPage "490" @default.
• W2022285477 startingPage "483" @default.
• W2022285477 abstract "The low-molecular-weight alkanes--methane, ethane, propane, and butane--are found in a wide range of terrestrial and extraterrestrial settings. The development of robust criteria for distinguishing abiogenic from biogenic alkanes is essential for current investigations of Mars' atmosphere and for future exobiology missions to other planets and moons. Here, we show that alkanes synthesized during gas-phase radical recombination reactions in electrical discharge experiments have values of δ(2)H(methane)>δ(2)H(ethane)>δ(2)H(propane), similar to those of the carbon isotopes. The distribution of hydrogen isotopes in gas-phase radical reactions is likely due to kinetic fractionations either (i) from the preferential incorporation of (1)H into longer-chain alkanes due to the more rapid rate of collisions of the smaller (1)H-containing molecules or (ii) by secondary ion effects. Similar δ(13)C(C1-C2+) and δ(2)H(C1-C2+) patterns may be expected in a range of extraterrestrial environments where gas-phase radical reactions dominate, including interstellar space, the atmosphere and liquid hydrocarbon lakes of Saturn's moon Titan, and the outer atmospheres of Jupiter, Saturn, Neptune, and Uranus. Radical recombination reactions at high temperatures and pressures may provide an explanation for the combined reversed δ(13)C(C1-C2+) and δ(2)H(C1-C2+) patterns of terrestrial alkanes documented at a number of high-temperature/pressure crustal sites." @default.
• W2022285477 created "2016-06-24" @default.
• W2022285477 creator A5062872049 @default.
• W2022285477 creator A5068880722 @default.
• W2022285477 creator A5070760760 @default.
• W2022285477 date "2013-05-01" @default.
• W2022285477 modified "2023-09-26" @default.
• W2022285477 title "Carbon and Hydrogen Isotopic Composition of Methane and C₂₊ Alkanes in Electrical Spark Discharge: Implications for Identifying Sources of Hydrocarbons in Terrestrial and Extraterrestrial Settings" @default.
• W2022285477 cites W1626129648 @default.
• W2022285477 cites W1963498224 @default.
• W2022285477 cites W1966007330 @default.
• W2022285477 cites W1966383398 @default.
• W2022285477 cites W1973982884 @default.
• W2022285477 cites W1974442790 @default.
• W2022285477 cites W1975562166 @default.
• W2022285477 cites W1978376111 @default.
• W2022285477 cites W1982283598 @default.
• W2022285477 cites W1983384197 @default.
• W2022285477 cites W1983782186 @default.
• W2022285477 cites W1986057012 @default.
• W2022285477 cites W1987478315 @default.
• W2022285477 cites W1988146940 @default.
• W2022285477 cites W1995603005 @default.
• W2022285477 cites W1995851907 @default.
• W2022285477 cites W1998919748 @default.
• W2022285477 cites W1999654984 @default.
• W2022285477 cites W2002647533 @default.
• W2022285477 cites W2008680648 @default.
• W2022285477 cites W2008759419 @default.
• W2022285477 cites W2020444159 @default.
• W2022285477 cites W2021519515 @default.
• W2022285477 cites W2024482144 @default.
• W2022285477 cites W2034324611 @default.
• W2022285477 cites W2034456397 @default.
• W2022285477 cites W2037367235 @default.
• W2022285477 cites W2038090715 @default.
• W2022285477 cites W2039066042 @default.
• W2022285477 cites W2039172699 @default.
• W2022285477 cites W2040502433 @default.
• W2022285477 cites W2043464527 @default.
• W2022285477 cites W2043468061 @default.
• W2022285477 cites W2048839862 @default.
• W2022285477 cites W2048909144 @default.
• W2022285477 cites W2051243780 @default.
• W2022285477 cites W2051724885 @default.
• W2022285477 cites W2053345529 @default.
• W2022285477 cites W2055538564 @default.
• W2022285477 cites W2065095882 @default.
• W2022285477 cites W2065423263 @default.
• W2022285477 cites W2067968569 @default.
• W2022285477 cites W2071466572 @default.
• W2022285477 cites W2072851944 @default.
• W2022285477 cites W2075179945 @default.
• W2022285477 cites W2091183826 @default.
• W2022285477 cites W2091813966 @default.
• W2022285477 cites W2095286551 @default.
• W2022285477 cites W2095380366 @default.
• W2022285477 cites W2095416313 @default.
• W2022285477 cites W2099880602 @default.
• W2022285477 cites W2103484151 @default.
• W2022285477 cites W2109162012 @default.
• W2022285477 cites W2111469003 @default.
• W2022285477 cites W2122661163 @default.
• W2022285477 cites W2135494969 @default.
• W2022285477 cites W2138337183 @default.
• W2022285477 cites W2139190083 @default.
• W2022285477 cites W2151971356 @default.
• W2022285477 cites W2153323573 @default.
• W2022285477 cites W2168336556 @default.
• W2022285477 cites W2172176411 @default.
• W2022285477 cites W3104535726 @default.
• W2022285477 cites W96572586 @default.
• W2022285477 doi "https://doi.org/10.1089/ast.2012.0915" @default.
• W2022285477 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23683048" @default.
• W2022285477 hasPublicationYear "2013" @default.
• W2022285477 type Work @default.
• W2022285477 sameAs 2022285477 @default.
• W2022285477 citedByCount "6" @default.
• W2022285477 countsByYear W20222854772017 @default.
• W2022285477 countsByYear W20222854772020 @default.
• W2022285477 countsByYear W20222854772022 @default.
• W2022285477 countsByYear W20222854772023 @default.
• W2022285477 crossrefType "journal-article" @default.
• W2022285477 hasAuthorship W2022285477A5062872049 @default.
• W2022285477 hasAuthorship W2022285477A5068880722 @default.
• W2022285477 hasAuthorship W2022285477A5070760760 @default.
• W2022285477 hasBestOaLocation W20222854772 @default.
• W2022285477 hasConcept C121332964 @default.
• W2022285477 hasConcept C178790620 @default.
• W2022285477 hasConcept C185592680 @default.
• W2022285477 hasConcept C2776345496 @default.
• W2022285477 hasConcept C50805821 @default.
• W2022285477 hasConcept C512968161 @default.
• W2022285477 hasConcept C516920438 @default.
• W2022285477 hasConcept C87355193 @default.
• W2022285477 hasConceptScore W2022285477C121332964 @default.
• W2022285477 hasConceptScore W2022285477C178790620 @default.
• W2022285477 hasConceptScore W2022285477C185592680 @default.

• next