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- W2022287495 abstract "A series of Pd(S)-[n(111)×(111)] and Pd(S)-[n(100)×(111)] electrodes give voltammograms in 0.5 M H2SO4, which depend remarkably on the surface structure. Pd surfaces with more than three atomic rows of terrace show redox peaks due to the desorption and adsorption of HSO4−/SO42− between 0.25 and 0.33 V (RHE). In the oxide film formation region, Pd(S)-[n(111)×(111)] electrodes give two anodic peaks at 0.95 and 1.1 V (RHE): the charge of the former peak increases with the increase of the step atom density, whereas that of the latter depends linearly on the terrace atom density. Pd(S)-[n(100)×(111)] electrodes provide an anodic peak at 0.93 V (RHE). The charge correlates with the terrace width. These electrodes give no peak for which the charge depends on the step density." @default.
- W2022287495 created "2016-06-24" @default.
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- W2022287495 date "2000-05-01" @default.
- W2022287495 modified "2023-10-14" @default.
- W2022287495 title "Voltammograms of the single-crystal electrodes of palladium in aqueous sulfuric acid electrolyte: Pd(S)-[n(111)×(111)] and Pd(S)-[n(100)×(111)]" @default.
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- W2022287495 doi "https://doi.org/10.1016/s0022-0728(00)00098-x" @default.
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