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- W2022294032 abstract "An S1 ring‐N(CH3)2 torsional potential function with V2≂3700 and V4≂−1450 cm−1 is deduced from the published spectrum [Grassian et al., J. Chem. Phys. 90, 3994 (1989)] of 4‐N,N‐dimethylaminobenzonitrile. The equilibrium conformation is twisted by 25°, and there are barriers of 185 and 3900 cm−1 at the planar and perpendicular conformations. Similar results are obtained for the (CD3)2 derivative, and for N,N‐dimethylaniline, 3‐N,N‐dimethylaminobenzonitrile, and 4‐(trifluoromethyl)‐N,N‐dimethylaniline." @default.
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- W2022294032 date "1990-11-01" @default.
- W2022294032 modified "2023-10-09" @default.
- W2022294032 title "Comment on: The torsional potential function of dimethylaminobenzonitrile and related compounds in their <i>S</i><sub>1</sub> states" @default.
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- W2022294032 doi "https://doi.org/10.1063/1.458924" @default.
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