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- W2022294158 abstract "A number of amine and ether complexes of (methylsulfinyl)methyllithium and sodium have been prepared and characterized. Complexes were only formed with the more strongly coordinating bases such as THF and dimethoxyethane; other bases, such as diethyl ether, did not complex, and uncomplexed LiCH2SOCH3 was isolated. The uncomplexed material, whether produced in a non-coordinating base or by desolvation of a complex, was extremely shock-sensitive, giving rapid spontaneous decomposition to sulfur-containing material. LiCH2SOCH3 reacted with acetylene to form an unstable complex of the formula (LiCCH)2 · CH3SOCH3." @default.
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- W2022294158 date "1970-08-01" @default.
- W2022294158 modified "2023-09-23" @default.
- W2022294158 title "Complexes of (methylsulfinyl)methyllithium and -sodium, with Lewis bases" @default.
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- W2022294158 doi "https://doi.org/10.1016/s0022-328x(00)91560-2" @default.
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