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- W2022301329 abstract "When argon matrices of MnX(CO)5, X = Br and Cl, containing dihydrogen are photolyzed with either visible light or light of 254 nm, a new species is formed which is MnX(η2-H2)(CO)4. The compounds have been characterized by infrared and Raman spectroscopies, and an energy-factored force field has been fit to the carbonyl modes. The structures can be thought of as arising from an octahedron with no halide and dihydrogen occupying cis-positions. While the H−H stretching vibration was not observed, the symmetric metal−hydrogen stretches have been observed at 788.6, 665.2, and 588.5 cm-1 for the adducts of H2, HD, and D2 and MnBr(CO)4, respectively. The same mode occurs at 764 cm-1 for MnCl(H2)(CO)4; hence, H2 is not strongly bound to the metal. An analysis of the carbonyl stretching force constants supports the view that H2 is not as strong of a π-acid as CO. The spectra of MnX(CO)4 have been re-examined, and it is clear that the features that had been previously assigned to MnX(CO)4 of C2v symmetry actually b..." @default.
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- W2022301329 date "1997-03-01" @default.
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- W2022301329 title "Synthesis and Characterization of Dihydrogen Complexes of Tetracarbonylbromomanganese(I) and Tetracarbonylchloromanganese(I) in Argon Matrices" @default.
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- W2022301329 doi "https://doi.org/10.1021/om960764g" @default.
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