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- W2022302057 abstract "1,4-Bis(trimethylsiloxy)benzene has been crystallized both by vacuum sublimation and from «-heptane solution, which each yielded colourless plates with identical monoclinic unit cell dimensions (P 2 /n, Z = 4). The conformation of C[ symmetry shows the two (H 3 C) 3 SiO-substituents to be conrotationally twisted around the O-( C 6 H 4 )-O axis by dihedral angles o f ± 60°. According to the photoelectron spectroscopic ionisation pattern and its Koopmans’ assignment, IE V n = -ε J AM 1 , by AM 1 eigenvalues, the gas phase structure should also be of C, symmetry. The results of geometry-optimized MNDO , AM 1 or PM 3 calculations for the monosubstituted derivative H 5 C 6 -OS i(CH 3 ) 3 are compared with respect to the quality of their fit to the measured data." @default.
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- W2022302057 date "1994-02-01" @default.
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- W2022302057 title "Strukturen sterisch überfüllter Moleküle, 39 [1,2]" @default.
- W2022302057 doi "https://doi.org/10.1515/znb-1994-0222" @default.
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