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- W2022302368 abstract "Abstract The photostabilities of three novel bicyclo-boron dipyrromethene difluoride dyes (bicyclo-BODIPY) in solution were investigated by measuring the fluorescence intensity as a function of accumulated 532 nm laser pulses. At 10 −6 M concentration 2-butanone and methanol solutions of the novel bicyclo-BODIPY dyes 1 and 2 exhibited photodegradation half-lives within 25% of the photodegradation half-life for 1,3,5,7,8-pentamethyl-2,6,-di- t -butyl pyrromethene difluoroborate (PM-597). At 10 −7 M the photostability of a 2-butanone solution of bicyclo-BODIPY 2 is only half that of PM-597. Bicyclo-BODIPY dyes 1 and 2 demonstrated maxima in the fluorescence vs. accumulated pulses plots, attributed to a fluorescent benzo intermediate produced by a retro Diels–Alder reaction." @default.
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- W2022302368 date "2002-12-01" @default.
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- W2022302368 title "Photostability studies of three new bicyclo-boron dipyrromethene difluoride dyes" @default.
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- W2022302368 doi "https://doi.org/10.1016/s0143-7208(02)00109-2" @default.
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