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- W2022302717 endingPage "6083" @default.
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- W2022302717 abstract "The jellium sphere model of a volume of electrons, counterbalanced by a positive charge throughout the sphere, leads to an energy level sequence corresponding to special stabilities of bare post-transition element clusters with 20 valence electrons such as the known P4 and clusters with 40 valence electrons such as the known Ge9(4-), Ni@In10(10-), and In11(7-). In this model the otherwise external lone pairs on the vertex atoms participate at least indirectly in the skeletal bonding. Furthermore, this model predicts the most favorable polyhedra and electron counts in some cases to be quite different than those predicted by the Wade-Mingos rules of polyhedral borane chemistry." @default.
- W2022302717 created "2016-06-24" @default.
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- W2022302717 date "2008-01-01" @default.
- W2022302717 modified "2023-09-30" @default.
- W2022302717 title "The role of “external” lone pairs in the chemical bonding of bare post-transition element clusters: the Wade–Mingos rules versus the jellium model" @default.
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- W2022302717 doi "https://doi.org/10.1039/b803958e" @default.
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