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• W2022302724 endingPage "401" @default.
• W2022302724 startingPage "391" @default.
• W2022302724 abstract "The rotational spectra of 2-methyloxetane and 3-methyloxetane have been reinvestigated using Fourier transform microwave spectroscopy (FTMW). A,E splittings due to internal rotation of the methyl group have been observed in the ground and several ring-puckering and methyl torsion excited states for both molecules. Internal rotation barriers of V3 = 3.332(14) kcal mol−1 (13.941(58) kJ mol−1) for 2-methyloxetane and V3 = 3.284(12) kcal mol−1 (13.740(50) kJ mol−1) for 3-methyloxetane have been determined from the ground vibrational state spectra. Furthermore, the rotational, quartic and some higher-order centrifugal distortion constants are reported. The experimental set-up of a waveguide Fourier transform microwave spectrometer is also presented." @default.
• W2022302724 created "2016-06-24" @default.
• W2022302724 creator A5015084638 @default.
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• W2022302724 creator A5043224024 @default.
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• W2022302724 date "1996-08-01" @default.
• W2022302724 modified "2023-10-16" @default.
• W2022302724 title "Fourier transform microwave study on 2-methyloxetane and 3-methyloxetane" @default.
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• W2022302724 doi "https://doi.org/10.1016/0301-0104(96)00090-0" @default.
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