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• W2022305129 abstract "The interaction of aldehydes, ketones, and amines with the organometallic Lewis acids [CpRuL1L2]+, where L1 = CO or PPh3 and L2 = PPh3, have been investigated, A series of Lewis acid-base adducts has been synthesized and characterized. Stable [CpRuL1L2(η1-HNCHPh)]+ complexes were isolated in high yields as the SbF6− or PF6− salts. X-Ray crystallographic analysis confirmed the η1-binding mode of the imine in [CpRu(PPh3)2(HNCHPh)]PF6 and the aldehyde carbonyl in [CpRu(PPh3)(CO)(cinnamaldehyde)]PF6. The effects of conformational isomerism in these systems have been investigated." @default.
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• W2022305129 date "1991-12-01" @default.
• W2022305129 modified "2023-10-06" @default.
• W2022305129 title "Ketone, aldehyde and aldimine complexes of cyclopentadienylruthenium organometallic Lewis acids" @default.
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• W2022305129 doi "https://doi.org/10.1016/0022-328x(91)80266-m" @default.
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