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- W2022306251 abstract "The impedance of heterogeneous platinum-gold alloys was measured at frequencies between 100 and 10,000 c/sec in the potential range between hydrogen and oxygen evolution by voltammetry with superimposed alternating voltage. The shape of the capacity-potential curves of the alloys with gold contents below 40 atomic % is largely determined by the platinum-rich phase of the alloys. Above 40 atomic % the gold-rich phase becomes increasingly predominant with gold content. Small amounts of the platinum-rich phase at the surface are recognizable up to 60 atomic % Au by the pseudocapacity of the Volmer reaction in the hydrogen region. The frequency dispersion of the double-layer impedance is attributed to the heterogeneity of the surface of the alloys." @default.
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- W2022306251 title "Capacity measurements on platinum-gold alloys in sulphuric acid solution" @default.
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