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- W2022307139 abstract "The self-association of crystal violet and ethyl violet in aqueous solution has been studied using multiwavelength linear regression of the concentration dependent absorbance data. Dimerization (K1) and trimerization (K2) equilibrium constants were determined to be 680 M−1 and 730 M−1 for crystal violet, respectively, and 3970 M−1 and 1180 M−1 for ethyl violet. Although not imposed by the numerical analysis of the data, resolved spectra of the dimer and trimer were obtained having approximately the same integrated absorptivity per mole of dye as that of the monomer. A reasonable model of the dimer structure is presented and discussed in terms of the excitonic coupling of the transition moments for the two visible bands in the momomer absorbance spectrum." @default.
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- W2022307139 title "Aggregation of triphenylmethane dyes in aqueous solution: Dimerization and trimerization of crystal violet and ethyl violet" @default.
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