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• W2022326029 endingPage "14510" @default.
• W2022326029 startingPage "14510" @default.
• W2022326029 abstract "Casiopeínas® are copper complexes with the general formula [Cu(N–N)(N–O)]NO3 and [Cu(N–N)(O–O)]NO3 where N–N denotes a substituted bipyridine or phenanthroline, N–O indicates α-aminoacidate or peptide and O–O represents acetylacetonate or salicylaldehyde. This family of compounds has been evaluated in vitro and in vivo showing cytotoxic, genotoxic, and antineoplastic activity. The action mechanism is still not completely elucidated, but the possibility exists that these compounds interact with DNA by intercalation due to the aromatic moiety. In this work we found, using the properties of the electron density of a π-complex model base–Casiopeína®–base, that the stacking mechanism between Casiopeínas® and DNA bases is due to an electron density deficiency of the ligand of the Casiopeína® which is compensated for by an electron transfer from adenines by a π–π interaction." @default.
• W2022326029 created "2016-06-24" @default.
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• W2022326029 creator A5081896966 @default.
• W2022326029 date "2011-01-01" @default.
• W2022326029 modified "2023-10-18" @default.
• W2022326029 title "π-Stacking between Casiopeinas® and DNA bases" @default.
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• W2022326029 doi "https://doi.org/10.1039/c1cp20183b" @default.
• W2022326029 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21748173" @default.
• W2022326029 hasPublicationYear "2011" @default.
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