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- W2022331544 abstract "The kinetics of oxidation of a series of benzene-1,2-diols by hexachloroiridate(IV) have been investigated by the stopped-flow technique in aqueous acidic perchlorate media. The reactions are first order in the concentrations of both reactants and independent of acidity and added [IrCl6]3–. The experimental results are discussed in the light of Marcus theorywith reference to previous findings on the kinetic behaviour of benzene-1,4-diols. The dependence of the free energies of activation on the free energies of reaction provides information on the mechanism of these non-complementary redox reactions." @default.
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- W2022331544 date "1977-01-01" @default.
- W2022331544 modified "2023-09-26" @default.
- W2022331544 title "Electron-transfer reactions of benzene-1,2-diols with hexachloroiridate(IV) in acidic perchlorate media" @default.
- W2022331544 doi "https://doi.org/10.1039/dt9770000132" @default.
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