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- W2022334477 abstract "The catalytic reaction of 1,3-butadiene with ethyl methylacetoacetate in the presence of (η2-1,3-butadiene)Pd(R2P(CH2)nPR2) compounds has been investigated. The product is a mixture of 1:1 adducts and the rate of reaction is highest when n2, RPri and in dichloromethane as solvent. Insight into the mechanism has been obtained by studying the stoichiometric reaction of (η2-1,3-butadiene)Pd(Pri2PC2H4PPri2) with the ester using variable temperature NMR spectroscopy and it has been shown that initially an [(η3-1-MeC3H4)-Pd(Pri2PC2H4Ppri2)]+ species is formed which reacts further to give (η2-alkene)Pd(Pri2PC2H4Ppri2) compounds in which the product of the catalysis is complexed to the palladium atom. The crystal structures of three side products, viz. Pd2(Pri2PCH2PPri2)2, [(η1,η3-C8H12)Pd]2(Me2PC2H4PMe2) and ClCH2Pd(Cy2PC2H4PCy2)Cl, have been determined by X-ray diffraction." @default.
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- W2022334477 date "1994-07-01" @default.
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- W2022334477 title "Intermediates in the palladium-catalysed reaction of 1,3-dienes Part 8. The reaction of palladium-butadiene complexes with ethyl methylacetoacetate" @default.
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- W2022334477 doi "https://doi.org/10.1016/0020-1693(94)03907-0" @default.
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