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- W2022342546 abstract "Abstract The molecular composition and thermodynamic properties of the equilibrium vapour species over condensed NaI-HoI 3 mixtures was investigated by Knudsen effusion mass spectrometry. Results show that in addition to the pure components (NaI(g), HoI 3 (g)) homocomplexes (Na 2 I 2 (g), Dy 2 I 6 (g)) and heterocomplexes (NaHoI 4 (g), Na 2 HoI 5 (g)) are formed in the saturated vapour. The second and third laws of thermodynamics were used for the determination of the thermodynamic parameters for homogeneous and heterogeneous processes. The resulting mean values are as follows: NaI ( s ) + HoI 3 ( s ) = NaHoI 4 ( g ); Δ r H o 298 K = 257.8 ± 6 kJ mol −1 , Δ r S o 298 K = 225.7 ± 8 mJ mol −1 K −1 . NaI ( g ) + HoI 3 ( s ) = NaHoI 4 ( g ); Δ r H o 298 K = 63.5 ± 4 kJ mol −1 , Δ r S o 298 K = 76.6 ± 6 J mol −1 K −1 . NaI ( s ) + HoI 3 ( g ) = NaHoI 4 ( g ); Δ r H o 298 K = −20.4 ± 7 kJ mol −1 , Δ r S o 298 K = 20 ± 9 J mol −1 K −1 . NaI ( g ) + HoI 3 ( g ) = NaHoI 4 ( g ); Δ r H o 298 K = −213.7 ± 5 kJ mol −1 , Δ r S o 298 K = −122.8 ± 4 J mol −1 K −1 ." @default.
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- W2022342546 date "1989-06-01" @default.
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- W2022342546 title "Molecular composition and thermodynamic equilibria in vapour over the NaI-HoI3 condensed phase" @default.
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- W2022342546 doi "https://doi.org/10.1016/0022-5088(89)90074-x" @default.
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