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• W2022350381 abstract "Electric-field-induced phase transitions have been evidenced by macroscopic strain measurements at temperatures between $25phantom{rule{0.2em}{0ex}}ifmmode^circelsetextdegreefi{}mathrm{C}$ and $100phantom{rule{0.2em}{0ex}}ifmmode^circelsetextdegreefi{}mathrm{C}$ in ${[001]}_{C}$-poled $(1ensuremath{-}x)mathrm{Pb}({mathrm{Mg}}_{1∕3}{mathrm{Nb}}_{2∕3}){mathrm{O}}_{3}ensuremath{-}xmathrm{Pb}mathrm{Ti}{mathrm{O}}_{3}phantom{rule{0.3em}{0ex}}[(mathrm{PMN}text{ensuremath{-}}xmathrm{PT});x=0.25,0.305,0.31]$ and $(1ensuremath{-}x)mathrm{Pb}({mathrm{Zn}}_{1∕3}{mathrm{Nb}}_{2∕3}){mathrm{O}}_{3}ensuremath{-}xmathrm{Pb}mathrm{Ti}{mathrm{O}}_{3}phantom{rule{0.3em}{0ex}}[(mathrm{PZN}text{ensuremath{-}}xmathrm{PT});x=0.05,0.065,0.085]$ single crystals. Such measurements provide a convenient way of ascertaining thermal and electrical phase stabilities over a range of compositions and give direct evidence for first-order phase transitions. A pseudorhombohedral $({M}_{A})$--pseudo-orthorhombic $({M}_{C})$--tetragonal $(T)$ polarization rotation path is evidenced by two first-order-like, hysteretic discontinuities in strain within the same unipolar electric field cycle for PZN-5PT, PMN-30.5PT, and PMN-31PT whereas, in PMN-25PT, a single first-order-like ${M}_{A}text{ensuremath{-}}T$ transition is observed. This agrees well with in situ structural studies reported elsewhere. Electric-field-temperature (E-T) phase diagrams are constructed showing general trends for ${M}_{A}$, ${M}_{C}$, and $T$ phase stabilities for varying temperatures and electric fields in poled samples over the given range of compositions. The complex question of whether the ${M}_{A}$ and ${M}_{C}$ states constitute true phases, or rather piezoelectrically distorted versions of their rhombohedral $(R)$ and orthorhombic $(O)$ parents, is discussed. Finally, stress-induced phase transitions are evidenced in ${[001]}_{C}$-poled PZN-4.5PT by application of a moderate compressive stress $(<100phantom{rule{0.3em}{0ex}}mathrm{MPa})$ both along and perpendicularly to the poling direction (longitudinal and transverse modes, respectively). The rotation path is likely $Rtext{ensuremath{-}}{M}_{B}text{ensuremath{-}}O$, via a first-order, hysteretic rotation within the ${M}_{B}$ monoclinic plane. The results are presented alongside a thorough review of previously reported electric-field-induced and stress-induced phase transitions in $mathrm{PMN}text{ensuremath{-}}xmathrm{PT}$ and $mathrm{PZN}text{ensuremath{-}}xmathrm{PT}$." @default.
• W2022350381 created "2016-06-24" @default.
• W2022350381 creator A5007423905 @default.
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• W2022350381 date "2006-01-27" @default.
• W2022350381 modified "2023-10-14" @default.
• W2022350381 title "Electric-field-, temperature-, and stress-induced phase transitions in relaxor ferroelectric single crystals" @default.
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• W2022350381 doi "https://doi.org/10.1103/physrevb.73.014115" @default.
• W2022350381 hasPublicationYear "2006" @default.
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