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• W2022350921 endingPage "2827" @default.
• W2022350921 startingPage "2815" @default.
• W2022350921 abstract "Lead zirconate titanate (PZT) ceramics with Zr/Ti ratios between 95/5 and 55/45 have been examined by transmission electron microscopy (TEM), dielectric spectroscopy, Sawyer-Tower polarization techniques, and dilatometric measurements. The relative phase stability in the high-Zr-content end of the PZT phase diagram is believed to be directly related to the coupling of the polarization to various oxygen octahedral rotational systems. The transformation between the high- and low-temperature rhombohedral ferroelectric phases (FER(HT)-FER(LT)) in PZT 90/10 was found to be associated with a transition between a high-temperature M-type and a low-temperature R-type oxygen octahedral rotational system. However, with increasing Ti content (Zr/Ti < 80/20), a transition between a disordered R-type tilted state to a low-temperature ordered R-type tilted state was found near the FER(HT)-FER(LT) boundary. The transition between the disordered and ordered R-type tilted states became increasingly gradual with increased Ti content. In the disordered R-type tilted state, local strains due to random octahedral rotations are believed to disrupt the long-range polar order, resulting in an inability to sustain a remnant polarization. A modified phase diagram illustrating the various oxygen octahedral tilted states and polarization behaviors is presented." @default.
• W2022350921 created "2016-06-24" @default.
• W2022350921 creator A5030714587 @default.
• W2022350921 creator A5037434358 @default.
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• W2022350921 date "1995-10-01" @default.
• W2022350921 modified "2023-09-25" @default.
• W2022350921 title "Effect of Oxygen Octahedron Rotations on the Phase Stability, Transformational Characteristics, and Polarization Behavior in the Lead Zirconate Titanate Crystalline Solution Series" @default.
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• W2022350921 doi "https://doi.org/10.1111/j.1151-2916.1995.tb08059.x" @default.
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