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• W2022353750 abstract "Abstract: Solid‐phase methodology was used to synthesize a series of fully reduced linear oligolysines (pseudooligolysines, abbreviated herein as PLs) containing up to five adjacent CH 2 NH peptide bond isosteres. The reduced peptide bonds were introduced by the reductive alkylation reaction between Fmoc‐Lys‐(Boc)‐al and a free α‐amine moiety on the pseudopeptidyl resin, using sodium cyanoborohydride in an acidified mixture of NMP/CH 3 OH (1 : 1 v/v). The oligomeric molecules, which can be regarded as polyethylene imine and spermine analogs, possess multiple positive charges under physiological conditions and form tight complexes with plasmid DNA. These characteristics and the increased resistance to hydrolysis by trypsin make these molecules potential candidates for future use as DNA carriers in gene delivery." @default.
• W2022353750 created "2016-06-24" @default.
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• W2022353750 date "2001-07-01" @default.
• W2022353750 modified "2023-09-29" @default.
• W2022353750 title "Systematic solid-phase synthesis of linear pseudooligolysines containing multiple adjacent CH₂NH amide bond surrogates: potential agents for gene delivery" @default.
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• W2022353750 doi "https://doi.org/10.1034/j.1399-3011.2001.00870.x" @default.
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