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- W2022355951 abstract "Elastic differential cross-section measurements of gaseous SF6 were made with 30 keV electrons in the range of 0.25 bohrs−1≤s≤10 bohrs−1. Structural parameters derived in this study closely matched those found in an earlier total (elastic plus inelastic) scattering investigation. Multiple-scattering effects were incorporated in the structural refinement. The discrepancies between the independent atom model and the measured differential cross section reproduce earlier total scattering results for momentum transfers of greater than 5 bohrs−1. By extending the measurements to smaller s values, a closer examination of a Hartree–Fock calculation for SF6 was possible. It was found that the difference curve obtained from the Hartree–Fock calculation matched the experimental data in this region. A more quantitative analysis was performed using the analytic expressions of Bonham and Fink to compute moments of the molecular charge distribution from the differential cross-section data. Comparison of these results with similar fits to the Hartree–Fock calculation confirmed the good agreement between the Hartree–Fock calculation and the current elastic data." @default.
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- W2022355951 title "Molecular bonding in SF<sub>6</sub> measured by elastic electron scattering" @default.
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