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- W2022359102 abstract "In acidic aqueous solution, oxidation of the β-amino alcohols [Formula: see text], I, and [Formula: see text], II, (R = H, alkyl) using the Ti(III)–H 2 O 2 flow technique gave the radicals [Formula: see text], and [Formula: see text]. The spectrum of [Formula: see text] shows restricted rotation about the C 1 —C 2 bond assigned to intramolecular hydrogen bonding.Under neutral conditions, oxidation of I gave the spectrum of •CH 2 CHO, and of II the acetonyl radical •CH 2 COCH 3 . It is proposed that elimination occurs by deprotonation of the abstraction radical in a hydrogen-bonded conformation, followed by rapid fragmentation to yield the α-carbonyl radical." @default.
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- W2022359102 date "1973-12-15" @default.
- W2022359102 modified "2023-10-05" @default.
- W2022359102 title "Electron Spin Resonance Studies in Aqueous Solution: Fragmentation of Radical Intermediates Derived from β-Amino Alcohols" @default.
- W2022359102 doi "https://doi.org/10.1139/v73-598" @default.
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