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- W2022359112 abstract "The kinetics and mechanism of high-temperature (120–140 °C) oxidation of p-xylene by molecular oxygen in a two-phase system have been studied in the presence of quaternary ammonium cations and bromide anions as catalysts. The reaction proceeds in the absence of any transition metals, and the quaternary ammonium cation is a phase-transfer agent for the radical precursor - bromide anion. The maximum absorption rate of oxygen can be expressed as follows: −dO2/dt = k[PX][Q]0.5[Br]0.5/[H2O]0.2 with k' = k[H2O]0.2=2.53×10−4 dm3 mol−1 s−1 at 125 °C. A proposed free-radical mechanism implies reaction of hydroperoxides with Br− as an initiation reaction." @default.
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- W2022359112 date "1988-11-01" @default.
- W2022359112 modified "2023-10-18" @default.
- W2022359112 title "Kinetics and mechanism of phase-transfer catalyzed oxidation of p-xylene by molecular oxygen" @default.
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- W2022359112 doi "https://doi.org/10.1016/0304-5102(88)85016-8" @default.
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