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- W2022359959 abstract "The equilateral trinuclear Mo(IV) ion of incomplete cubane-type structure, Mo3S4+4, was prepared by the reduction of [Mo2O2S2(cys)2]2− with NaBH4 followed by air oxidation and Sephadex G-10 separation. The resultant green solution was analyzed to give S/Mo = 1.33. The spectrum {λmax[ε(M−1cm−1)]:367(5190), 500sh(290) and 602(351) in 2 M HPTS} remains unchanged in the air. The existence of the Mo3S4 core has been confirmed by X-ray structure analysis of Ca[Mo3S4(ida)3] · 11.5H2O (H2ida = iminodiacetic acid) which was prepared from the Mo3S4+4 ion and H2ida. Crystal data : orthorhombic, a = 13.815(3) Å, b = 26.189(9) Å, c = 9.447(3) Å, V = 3417.9(17) Å3, Z = 4, Dc = 2.053 g cm−3, space group P212121. R value is 0.048 for 3705 reflections [Fo ⩾ 3σ(Fo)]. The anion [Mo3S4(ida)3]2− has an approximate symmetry of C3ν and contains an incomplete cubane-type Mo3S4 core. Selected mean bond distances are as follows: MoMo, 2.754 Å, Moμ3-S, 2.349 Å; Moμ2-S, 2.295 Å; MoO, 2.167 Å, MoN, 2.227 Å. The existence of an [Mo(IV)]]2Mo(III) oxidation state has been indicated for the first time from the cyclic voltammogram and polarogram of the anion." @default.
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- W2022359959 date "1986-01-01" @default.
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- W2022359959 title "Preparation of trinuclear molybdenum(IV) ion, Mo3S4+4, and x-ray structure of Ca[Mo3S4 {HN(CH2CO2)2}3] · 11.5H2O" @default.
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- W2022359959 doi "https://doi.org/10.1016/s0277-5387(00)84933-5" @default.
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