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- W2022362145 abstract "There has been much disagreement about the origin of the 90 K transition temperature plateau in YBa2Cu3O7−δ. It is argued that the “90 K plateau” for YBa2Cu3O7−δ is simply the peak of the parabolic curve of Tc as a function of hole concentration and that when δ≈0 then 1–2–3 is slightly overdoped by 0.03 to 0.04 holes per copper. This is demonstrated from studies on altervalent substitutions, oxygen deficiency, comparison with 1–2–4 and 2–4–7, thermoelectric power, normal state susceptibility, structural data and bond valence sums, muon spin relaxation, Raman studies on the δ-dependence of the superconducting energy gap, and the pressure dependence of Tc. It is also shown that cation-stoichiometric LaBa2Cu3O7 should have Tc max≈100 K." @default.
- W2022362145 created "2016-06-24" @default.
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- W2022362145 date "1993-01-01" @default.
- W2022362145 modified "2023-09-28" @default.
- W2022362145 title "Stoichiometric YBa2Cu3O7 is overdoped" @default.
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- W2022362145 doi "https://doi.org/10.1016/0921-4534(93)91005-g" @default.
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