Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022362276> ?p ?o ?g. }
Showing items 1 to 70 of
70
with 100 items per page.
- W2022362276 endingPage "110" @default.
- W2022362276 startingPage "95" @default.
- W2022362276 abstract "Thermolysis of polyethylene hydroperoxides restricted to the initial stages can be readily understood. The same is true for the oxidation products formed on thermolysis. These products are essentially the same as those formed on processing in mixers open to air. They are mainly alcohols and ketones, in-the chain ketones and methyl-ketones. Carboxylic acids and aldehydes are also formed in a small amount. The same is valid for trans-vinylene and γ-lactone groups. The kinetics of oxidation product formation in the initial stages are clearly related to the corresponding kinetics for hydroperoxide decomposition. However, the various products show significant differences in this respect. Thus, thermolysis of hydroperoxides in the initial stages consists of direct hydroperoxide decomposition and free radical induced hydroperoxide decomposition. Formation of carbonyl groups corresponds also to such a process. This means that carbonyl groups result from both direct and induced hydroperoxide decomposition. However, alcohol groups are formed essentially in reactions following direct hydroperoxide decomposition according to the pseudo-monomolecular reaction. Formation of γ-lactones does not proceed according to the same general scheme. Its rate is increasing considerably with the initial oxidation of the samples. Hence, it looks as if it were formed out of products accumulating in the oxidizing polyethylene melt." @default.
- W2022362276 created "2016-06-24" @default.
- W2022362276 creator A5087751080 @default.
- W2022362276 date "2002-01-01" @default.
- W2022362276 modified "2023-09-27" @default.
- W2022362276 title "Thermolysis of polyethylene hydroperoxides in the melt3. Experimental kinetics of product formation" @default.
- W2022362276 cites W1593006649 @default.
- W2022362276 cites W1945237966 @default.
- W2022362276 cites W1968181877 @default.
- W2022362276 cites W1969915445 @default.
- W2022362276 cites W1985750594 @default.
- W2022362276 cites W2015481060 @default.
- W2022362276 cites W2028641825 @default.
- W2022362276 cites W2041210540 @default.
- W2022362276 doi "https://doi.org/10.1016/s0141-3910(02)00002-2" @default.
- W2022362276 hasPublicationYear "2002" @default.
- W2022362276 type Work @default.
- W2022362276 sameAs 2022362276 @default.
- W2022362276 citedByCount "19" @default.
- W2022362276 countsByYear W20223622762012 @default.
- W2022362276 countsByYear W20223622762015 @default.
- W2022362276 countsByYear W20223622762018 @default.
- W2022362276 countsByYear W20223622762021 @default.
- W2022362276 crossrefType "journal-article" @default.
- W2022362276 hasAuthorship W2022362276A5087751080 @default.
- W2022362276 hasConcept C121332964 @default.
- W2022362276 hasConcept C124681953 @default.
- W2022362276 hasConcept C148898269 @default.
- W2022362276 hasConcept C160434732 @default.
- W2022362276 hasConcept C178790620 @default.
- W2022362276 hasConcept C185592680 @default.
- W2022362276 hasConcept C188027245 @default.
- W2022362276 hasConcept C2779751980 @default.
- W2022362276 hasConcept C2781066024 @default.
- W2022362276 hasConcept C62520636 @default.
- W2022362276 hasConcept C75473681 @default.
- W2022362276 hasConcept C77176794 @default.
- W2022362276 hasConceptScore W2022362276C121332964 @default.
- W2022362276 hasConceptScore W2022362276C124681953 @default.
- W2022362276 hasConceptScore W2022362276C148898269 @default.
- W2022362276 hasConceptScore W2022362276C160434732 @default.
- W2022362276 hasConceptScore W2022362276C178790620 @default.
- W2022362276 hasConceptScore W2022362276C185592680 @default.
- W2022362276 hasConceptScore W2022362276C188027245 @default.
- W2022362276 hasConceptScore W2022362276C2779751980 @default.
- W2022362276 hasConceptScore W2022362276C2781066024 @default.
- W2022362276 hasConceptScore W2022362276C62520636 @default.
- W2022362276 hasConceptScore W2022362276C75473681 @default.
- W2022362276 hasConceptScore W2022362276C77176794 @default.
- W2022362276 hasIssue "1" @default.
- W2022362276 hasLocation W20223622761 @default.
- W2022362276 hasOpenAccess W2022362276 @default.
- W2022362276 hasPrimaryLocation W20223622761 @default.
- W2022362276 hasRelatedWork W1574527681 @default.
- W2022362276 hasRelatedWork W1993525157 @default.
- W2022362276 hasRelatedWork W1996952545 @default.
- W2022362276 hasRelatedWork W2018878625 @default.
- W2022362276 hasRelatedWork W2054847710 @default.
- W2022362276 hasRelatedWork W2070216242 @default.
- W2022362276 hasRelatedWork W2078010807 @default.
- W2022362276 hasRelatedWork W2147427301 @default.
- W2022362276 hasRelatedWork W4206660088 @default.
- W2022362276 hasRelatedWork W2476368235 @default.
- W2022362276 hasVolume "76" @default.
- W2022362276 isParatext "false" @default.
- W2022362276 isRetracted "false" @default.
- W2022362276 magId "2022362276" @default.
- W2022362276 workType "article" @default.