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• W2022363984 abstract "We have studied the growth of ultrathin (< 50 Å) Cu overlayers on stoichiometric TiO2(110) surfaces. Using low energy ion scattering, the growth mode of Cu was determined to be Volmer-Weber type (three-dimensional islands) at room temperature; evidence for cluster growth is observed even at 160 K. A comparison with Fe and Cr metal films shows that the spreading of the films correlates with the heat of formation of the metal oxide of the overlayer. Fe and Cr cause a reduction of the Ti4+ surface cations at the metal/metal oxide interface as observed with X-ray photoelectron spectroscopy. No reduction of the TiO2 cations takes place upon contact with a Cu overlayer." @default.
• W2022363984 created "2016-06-24" @default.
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• W2022363984 date "1993-05-01" @default.
• W2022363984 modified "2023-10-14" @default.
• W2022363984 title "Ultrathin metal films on TiO2(110): metal overlayer spreading and surface reactivity" @default.
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• W2022363984 doi "https://doi.org/10.1016/0039-6028(93)91095-7" @default.
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