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- W2022367385 abstract "Abstract Reactions of 1,4-diazabicyclo[2.2.2]octane (“dabco”) with K 2 [HgI 4 ] or Hg(SCN) 2 yield crystals of [Hg(dabco)I 2 ] (1) and [Hg(dabco)(SCN) 2 ] (2). 1 crystallizes monoclinically, space group P2 1 /a. Z = 4, a = 1211.6(5), b = 682.3(6), c = 1430.4(3) pm, β = 98.90(5)°; 2 is orthorhombic, space group Pmmn, Z = 2, a - 740.5(3), b = 609.1(4), c = 1220.0(8) pm. In 1 HgI 2 groups are connected by bridging dabco molecules to give a chain structure. The Hg atoms are tetrahedrally coordinated. In 2 the Hg atoms are bridged by two SCN ligands and the chains thus formed are again interconnected by bridging dabco molecules, whereby layers are formed. The coordination polyhedron for the Hg atoms is a distorted octahedron." @default.
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- W2022367385 title "Kristallstrukturen der „supramolekularen“ 1,4-Diazabicyclo[2.2.2]octan- Quecksilber(II)-Komplexe [Hg(dabco)I2] und [Hg(dabco)(SCN)2] / Crystal Structures of the “Supram olecular” 1,4-Diazabicyclo[2.2.2]octane Mercury(II) Complexes [Hg(dabco)I2] and [Hg(dabco)(SCN)2]" @default.
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