Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022367804> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W2022367804 endingPage "15308" @default.
- W2022367804 startingPage "15305" @default.
- W2022367804 abstract "The vibrational spectra of Na+(CH3OH)2-7 in the 2.7−3.0 μm region have been measured using a LiNbO3 optical parametric oscillator and a triple-quadrupole molecular beam apparatus. The cluster ions are formed by the impact of a sodium ion with a preformed methanol cluster. Frequency shifts of the methanol O−H stretch are used to identify both the onset of hydrogen-bond formation and the nature of the hydrogen-bonded species in the cluster ions, permitting the microscopic characterization of the solvation process. Methanol molecules associated with the cluster ion, but not acting as proton donors in a hydrogen bond, absorb in the 3660−70 cm-1 region, while bands due to hydrogen-bonded species have been observed at ∼3515, 3420, and 3350 cm-1. The onset of hydrogen-bond formation is nominally first observed for Na+(CH3OH)4, with more extensive hydrogen bonding observed for Na+(CH3OH)5-7. An assessment of the influence of the sodium ion on the methanol vibrational frequencies can be made through comparison with the spectra of Cs+(CH3OH)1-5 and (CH3OH)2-3. The effect of the electrostatic interaction, between either the sodium or cesium ion and the methanol solvent, is primarily reflected by the onset and extent of hydrogen-bond formation as opposed to the magnitude of vibrational spectroscopic shifts." @default.
- W2022367804 created "2016-06-24" @default.
- W2022367804 creator A5015467532 @default.
- W2022367804 creator A5072496984 @default.
- W2022367804 date "1996-01-01" @default.
- W2022367804 modified "2023-09-27" @default.
- W2022367804 title "Gas-Phase Cluster Ion Vibrational Spectroscopy of Na<sup>+</sup>(CH<sub>3</sub>OH)<sub>2-7</sub>" @default.
- W2022367804 cites W1979980334 @default.
- W2022367804 cites W1982035797 @default.
- W2022367804 cites W1985630174 @default.
- W2022367804 cites W2006709321 @default.
- W2022367804 cites W2022377884 @default.
- W2022367804 cites W2025751572 @default.
- W2022367804 cites W2026978019 @default.
- W2022367804 cites W2030756754 @default.
- W2022367804 cites W2046969441 @default.
- W2022367804 cites W2061126026 @default.
- W2022367804 cites W2062081084 @default.
- W2022367804 cites W2069285430 @default.
- W2022367804 cites W2080030733 @default.
- W2022367804 cites W2080614103 @default.
- W2022367804 cites W2083881961 @default.
- W2022367804 cites W2087179217 @default.
- W2022367804 cites W2088372335 @default.
- W2022367804 cites W2093826040 @default.
- W2022367804 cites W2952262185 @default.
- W2022367804 cites W4234182104 @default.
- W2022367804 doi "https://doi.org/10.1021/jp9621787" @default.
- W2022367804 hasPublicationYear "1996" @default.
- W2022367804 type Work @default.
- W2022367804 sameAs 2022367804 @default.
- W2022367804 citedByCount "58" @default.
- W2022367804 countsByYear W20223678042012 @default.
- W2022367804 countsByYear W20223678042013 @default.
- W2022367804 countsByYear W20223678042017 @default.
- W2022367804 countsByYear W20223678042018 @default.
- W2022367804 countsByYear W20223678042019 @default.
- W2022367804 countsByYear W20223678042023 @default.
- W2022367804 crossrefType "journal-article" @default.
- W2022367804 hasAuthorship W2022367804A5015467532 @default.
- W2022367804 hasAuthorship W2022367804A5072496984 @default.
- W2022367804 hasConcept C112887158 @default.
- W2022367804 hasConcept C113196181 @default.
- W2022367804 hasConcept C145148216 @default.
- W2022367804 hasConcept C147789679 @default.
- W2022367804 hasConcept C148093993 @default.
- W2022367804 hasConcept C164866538 @default.
- W2022367804 hasConcept C178790620 @default.
- W2022367804 hasConcept C185592680 @default.
- W2022367804 hasConcept C199360897 @default.
- W2022367804 hasConcept C2779607525 @default.
- W2022367804 hasConcept C2780471494 @default.
- W2022367804 hasConcept C32909587 @default.
- W2022367804 hasConcept C41008148 @default.
- W2022367804 hasConcept C512968161 @default.
- W2022367804 hasConceptScore W2022367804C112887158 @default.
- W2022367804 hasConceptScore W2022367804C113196181 @default.
- W2022367804 hasConceptScore W2022367804C145148216 @default.
- W2022367804 hasConceptScore W2022367804C147789679 @default.
- W2022367804 hasConceptScore W2022367804C148093993 @default.
- W2022367804 hasConceptScore W2022367804C164866538 @default.
- W2022367804 hasConceptScore W2022367804C178790620 @default.
- W2022367804 hasConceptScore W2022367804C185592680 @default.
- W2022367804 hasConceptScore W2022367804C199360897 @default.
- W2022367804 hasConceptScore W2022367804C2779607525 @default.
- W2022367804 hasConceptScore W2022367804C2780471494 @default.
- W2022367804 hasConceptScore W2022367804C32909587 @default.
- W2022367804 hasConceptScore W2022367804C41008148 @default.
- W2022367804 hasConceptScore W2022367804C512968161 @default.
- W2022367804 hasIssue "38" @default.
- W2022367804 hasLocation W20223678041 @default.
- W2022367804 hasOpenAccess W2022367804 @default.
- W2022367804 hasPrimaryLocation W20223678041 @default.
- W2022367804 hasRelatedWork W1618199886 @default.
- W2022367804 hasRelatedWork W2022370217 @default.
- W2022367804 hasRelatedWork W2036511834 @default.
- W2022367804 hasRelatedWork W2040950115 @default.
- W2022367804 hasRelatedWork W2054342626 @default.
- W2022367804 hasRelatedWork W2142469308 @default.
- W2022367804 hasRelatedWork W2318047532 @default.
- W2022367804 hasRelatedWork W3089127040 @default.
- W2022367804 hasRelatedWork W3147868310 @default.
- W2022367804 hasRelatedWork W4225796855 @default.
- W2022367804 hasVolume "100" @default.
- W2022367804 isParatext "false" @default.
- W2022367804 isRetracted "false" @default.
- W2022367804 magId "2022367804" @default.
- W2022367804 workType "article" @default.