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• W2022369080 abstract "The kinetics of the gas-phase reaction of Cl atoms with CF3I have been studied relative to the reaction of Cl atoms with CH4 over the temperature range 271–363 K. Using k(Cl + CH4) = 9.6 × 10−12 exp(−2680/RT) cm3 molecule−1 s−1, we derive k(Cl + CF3I) = 6.25 × 10−11 exp(−2970/RT) in which Ea has units of cal mol−1. CF3 radicals are produced from the reaction of Cl with CF3I in a yield which was indistinguishable from 100%. Other relative rate constant ratios measured at 296 K during these experiments were k(Cl + C2F5I)/k(Cl + CF3I) = 11.0 ± 0.6 and k(Cl + C2F5I)/k(Cl + C2H5Cl) = 0.49 ± 0.02. The reaction of CF3 radicals with Cl2 was studied relative to that with O2 at pressures from 4 to 700 torr of N2 diluent. By using the published absolute rate constants for k(CF3 + O2) at 1–10 torr to calibrate the pressure dependence of these relative rate constants, values of the low- and high-pressure limiting rate constants have been determined at 296 K using a Troe expression: k0(CF3 + O2) = (4.8 ± 1.2) × 10−29 cm6 molecule−2 s−1; k∞(CF3 + O2) = (3.95 ± 0.25) × 10−12 cm3 molecule−1 s−1; Fc = 0.46. The value of the rate constant k(CF3 + Cl2) was determined to be (3.5 ± 0.4) × 10−14 cm3 molecule−1 s−1 at 296 K. The reaction of Cl atoms with CF3I is a convenient way to prepare CF3 radicals for laboratory study. © 1995 John Wiley & Sons, Inc." @default.
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• W2022369080 date "1995-03-01" @default.
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• W2022369080 title "Kinetic study of the reaction of chlorine atoms with CF3I and the reactions of CF3 radicals with O2, Cl2 and NO at 296 K" @default.
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• W2022369080 doi "https://doi.org/10.1002/kin.550270302" @default.
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