Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022370217> ?p ?o ?g. }
Showing items 1 to 66 of
66
with 100 items per page.
- W2022370217 endingPage "1006" @default.
- W2022370217 startingPage "1001" @default.
- W2022370217 abstract "The kinetics of oxidation of [Co(en) 2 SCH 2 COO] + with S 2 O 8 2- was studied in water-methanol and water-tert-butyl alcohol mixtures. Changes in the reaction activation parameters ∆ H ≠ and ∆ S ≠ with varying concentration of the co-solvent depend on the kind of the latter, which points to a significant role of salvation effects. The solvation effect on the reaction is discussed based on a comparison of the transfer functions ∆ H t 0 , ∆ S t 0 and ∆ G t 0 for the initial and transition states with the changes in the activation parameters accompanying changes in the CO-solvent concentration. The transfer enthalpies of the reactant were obtained from calorimetric measurements." @default.
- W2022370217 created "2016-06-24" @default.
- W2022370217 creator A5005454450 @default.
- W2022370217 creator A5087985788 @default.
- W2022370217 date "1993-01-01" @default.
- W2022370217 modified "2023-10-17" @default.
- W2022370217 title "Thermodynamic and Kinetic Investigation of the Solvent Effect on the Oxidation of [Co(en)2SCH2COO]+ with S2O82- In Water-Methanol and Water-tert-Butyl Alcohol Mixtures" @default.
- W2022370217 doi "https://doi.org/10.1135/cccc19931001" @default.
- W2022370217 hasPublicationYear "1993" @default.
- W2022370217 type Work @default.
- W2022370217 sameAs 2022370217 @default.
- W2022370217 citedByCount "4" @default.
- W2022370217 crossrefType "journal-article" @default.
- W2022370217 hasAuthorship W2022370217A5005454450 @default.
- W2022370217 hasAuthorship W2022370217A5087985788 @default.
- W2022370217 hasConcept C121332964 @default.
- W2022370217 hasConcept C132439834 @default.
- W2022370217 hasConcept C135889238 @default.
- W2022370217 hasConcept C147789679 @default.
- W2022370217 hasConcept C148093993 @default.
- W2022370217 hasConcept C148898269 @default.
- W2022370217 hasConcept C178790620 @default.
- W2022370217 hasConcept C179104552 @default.
- W2022370217 hasConcept C185592680 @default.
- W2022370217 hasConcept C2779607525 @default.
- W2022370217 hasConcept C2780471494 @default.
- W2022370217 hasConcept C2781066024 @default.
- W2022370217 hasConcept C62520636 @default.
- W2022370217 hasConcept C95121573 @default.
- W2022370217 hasConcept C97355855 @default.
- W2022370217 hasConceptScore W2022370217C121332964 @default.
- W2022370217 hasConceptScore W2022370217C132439834 @default.
- W2022370217 hasConceptScore W2022370217C135889238 @default.
- W2022370217 hasConceptScore W2022370217C147789679 @default.
- W2022370217 hasConceptScore W2022370217C148093993 @default.
- W2022370217 hasConceptScore W2022370217C148898269 @default.
- W2022370217 hasConceptScore W2022370217C178790620 @default.
- W2022370217 hasConceptScore W2022370217C179104552 @default.
- W2022370217 hasConceptScore W2022370217C185592680 @default.
- W2022370217 hasConceptScore W2022370217C2779607525 @default.
- W2022370217 hasConceptScore W2022370217C2780471494 @default.
- W2022370217 hasConceptScore W2022370217C2781066024 @default.
- W2022370217 hasConceptScore W2022370217C62520636 @default.
- W2022370217 hasConceptScore W2022370217C95121573 @default.
- W2022370217 hasConceptScore W2022370217C97355855 @default.
- W2022370217 hasIssue "5" @default.
- W2022370217 hasLocation W20223702171 @default.
- W2022370217 hasOpenAccess W2022370217 @default.
- W2022370217 hasPrimaryLocation W20223702171 @default.
- W2022370217 hasRelatedWork W1970053198 @default.
- W2022370217 hasRelatedWork W1989940360 @default.
- W2022370217 hasRelatedWork W2015321541 @default.
- W2022370217 hasRelatedWork W2022370217 @default.
- W2022370217 hasRelatedWork W2035721937 @default.
- W2022370217 hasRelatedWork W2073264102 @default.
- W2022370217 hasRelatedWork W2077963663 @default.
- W2022370217 hasRelatedWork W2095641479 @default.
- W2022370217 hasRelatedWork W2360506645 @default.
- W2022370217 hasRelatedWork W2530980950 @default.
- W2022370217 hasVolume "58" @default.
- W2022370217 isParatext "false" @default.
- W2022370217 isRetracted "false" @default.
- W2022370217 magId "2022370217" @default.
- W2022370217 workType "article" @default.