FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022372654> ?p ?o ?g. }

• W2022372654 endingPage "2689" @default.
• W2022372654 startingPage "2683" @default.
• W2022372654 abstract "Abstract (4‐Methylpyridin‐2‐yl)(trimethylsilyl)amine ( 1 ), (6‐methylpyridin‐2‐yl)(trimethylsilyl)amine ( 2 ), and (2,6‐diisopropylphenyl)(pyridin‐2‐yl)amine ( 3 ) were deprotonated and used as ligands to synthesize trialkyltantalum complexes. The reaction of 2 equiv. of 1 or 2 with pentabenzyltantalum afforded tribenzyltantalum( V ) complexes by toluene elimination. Analogous reaction using 3 failed. Lithiation of 3 followed by the reaction with tribenzyltantalum dichloride gave rise to the corresponding tribenzyl complex. Other alkyltantalum complexes stabilized by this ligand environment can be prepared by treating tantalum pentachloride with 2 equiv. oflithiated 3 to form a bis(aminopyridinato)tantalum trichloride. The reaction of this trichloride with 3 equiv. of alkyllithium compounds like methyllithium affords the corresponding trialkyltantalum complexes. X‐ray diffraction studies of four of the synthesi z ed complexes were carried out. They adopt two different coordination environments, either slightly distorted capped octahedrons (sterically less demanding aminopyridinato ligands) or pentagonal bipyramids (bulkier aminopyridinato ligands). The alkyl species were surprisingly stable at elevated temperatures and no formation of mixed alkyl/alkylidene complexes was observed. Alkyl cation formation and the behaviour of a selection of these compounds in olefin polymerization were explored. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
• W2022372654 created "2016-06-24" @default.
• W2022372654 creator A5050773293 @default.
• W2022372654 creator A5061603797 @default.
• W2022372654 creator A5080790397 @default.
• W2022372654 date "2006-06-19" @default.
• W2022372654 modified "2023-10-12" @default.
• W2022372654 title "Synthesis and Structure of Trialkyltantalum Complexes Stabilized by Aminopyridinato Ligands" @default.
• W2022372654 cites W1965458378 @default.
• W2022372654 cites W1969635440 @default.
• W2022372654 cites W1970723518 @default.
• W2022372654 cites W1980383279 @default.
• W2022372654 cites W1985117281 @default.
• W2022372654 cites W1985187535 @default.
• W2022372654 cites W1986106140 @default.
• W2022372654 cites W1988731442 @default.
• W2022372654 cites W1989682290 @default.
• W2022372654 cites W1990148488 @default.
• W2022372654 cites W1996306169 @default.
• W2022372654 cites W1999338745 @default.
• W2022372654 cites W2000290946 @default.
• W2022372654 cites W2011316080 @default.
• W2022372654 cites W2012226759 @default.
• W2022372654 cites W2013588355 @default.
• W2022372654 cites W2013855714 @default.
• W2022372654 cites W2014289079 @default.
• W2022372654 cites W2014469098 @default.
• W2022372654 cites W2015712887 @default.
• W2022372654 cites W2018291969 @default.
• W2022372654 cites W2022036815 @default.
• W2022372654 cites W2026226750 @default.
• W2022372654 cites W2030340979 @default.
• W2022372654 cites W2040602303 @default.
• W2022372654 cites W2044515925 @default.
• W2022372654 cites W2044932558 @default.
• W2022372654 cites W2062982132 @default.
• W2022372654 cites W2063334178 @default.
• W2022372654 cites W2063392340 @default.
• W2022372654 cites W2065072227 @default.
• W2022372654 cites W2066918689 @default.
• W2022372654 cites W2067047597 @default.
• W2022372654 cites W2071872477 @default.
• W2022372654 cites W2074146676 @default.
• W2022372654 cites W2079449434 @default.
• W2022372654 cites W2080545005 @default.
• W2022372654 cites W2088437441 @default.
• W2022372654 cites W2093249481 @default.
• W2022372654 cites W2095487591 @default.
• W2022372654 cites W2102208605 @default.
• W2022372654 cites W2118916348 @default.
• W2022372654 cites W2128963180 @default.
• W2022372654 cites W2133288268 @default.
• W2022372654 cites W2154961866 @default.
• W2022372654 cites W2157528945 @default.
• W2022372654 cites W2312514786 @default.
• W2022372654 cites W76892053 @default.
• W2022372654 doi "https://doi.org/10.1002/ejic.200600120" @default.
• W2022372654 hasPublicationYear "2006" @default.
• W2022372654 type Work @default.
• W2022372654 sameAs 2022372654 @default.
• W2022372654 citedByCount "18" @default.
• W2022372654 countsByYear W20223726542013 @default.
• W2022372654 countsByYear W20223726542015 @default.
• W2022372654 countsByYear W20223726542017 @default.
• W2022372654 countsByYear W20223726542018 @default.
• W2022372654 countsByYear W20223726542019 @default.
• W2022372654 countsByYear W20223726542021 @default.
• W2022372654 crossrefType "journal-article" @default.
• W2022372654 hasAuthorship W2022372654A5050773293 @default.
• W2022372654 hasAuthorship W2022372654A5061603797 @default.
• W2022372654 hasAuthorship W2022372654A5080790397 @default.
• W2022372654 hasConcept C116569031 @default.
• W2022372654 hasConcept C118629725 @default.
• W2022372654 hasConcept C131779359 @default.
• W2022372654 hasConcept C145148216 @default.
• W2022372654 hasConcept C155647269 @default.
• W2022372654 hasConcept C161790260 @default.
• W2022372654 hasConcept C170493617 @default.
• W2022372654 hasConcept C178790620 @default.
• W2022372654 hasConcept C185592680 @default.
• W2022372654 hasConcept C188027245 @default.
• W2022372654 hasConcept C201194858 @default.
• W2022372654 hasConcept C2777000832 @default.
• W2022372654 hasConcept C2777775765 @default.
• W2022372654 hasConcept C2779743861 @default.
• W2022372654 hasConcept C2780263894 @default.
• W2022372654 hasConcept C30095370 @default.
• W2022372654 hasConcept C514619126 @default.
• W2022372654 hasConcept C55493867 @default.
• W2022372654 hasConcept C71240020 @default.
• W2022372654 hasConceptScore W2022372654C116569031 @default.
• W2022372654 hasConceptScore W2022372654C118629725 @default.
• W2022372654 hasConceptScore W2022372654C131779359 @default.
• W2022372654 hasConceptScore W2022372654C145148216 @default.
• W2022372654 hasConceptScore W2022372654C155647269 @default.
• W2022372654 hasConceptScore W2022372654C161790260 @default.
• W2022372654 hasConceptScore W2022372654C170493617 @default.
• W2022372654 hasConceptScore W2022372654C178790620 @default.

• next