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- W2022373300 abstract "Abstract The kinetics of thermolysis of sucrose in solution in anhydrous dimethyl sulphoxide have been studied. The reaction appears to be facilitated by intramolecular hydrogen-bonding and is inhibited by intermolecular hydrogen-bonding to water or alcohols. The thermolysis yields α- d -glucopyranose (which then anomerises) and the fructofuranosyl carbonium ion which can react with benzyl alcohol to yield benzyl α- and β- d -fructofuranosides. This fructosyl cation is probably also the precursor for the formation of 2,6-anhydrofructofuranose in the thermolysis of sucrose." @default.
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- W2022373300 date "1980-12-01" @default.
- W2022373300 modified "2023-09-30" @default.
- W2022373300 title "Thermolysis of sucrose in dimethyl sulphoxide solution" @default.
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- W2022373300 doi "https://doi.org/10.1016/s0008-6215(00)85207-6" @default.
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