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• W2022373676 abstract "Abstract Uniform metal (hydrous) oxide and their related particles were produced from the corresponding complex solutions of exothermic formation at elevated temperatures. The procedures could be combined with redox reactions for this purpose. As examples, preparation of the following uniform particles was undertaken for α -iron(III) oxide (hematite) from the glycinatoiron(III) and the 2,2′-bipyridineiron(II) complexes, aluminum(III) hydrous oxide from the acetylacetonato complex, manganese(II) carbonate from the sulfatomanganese(II) complex, copper(I) oxide, silver and lanthanum(III) carbonate hydroxide from the corresponding 1,2-ethanediamino complexes, and germanium(IV) oxide from the oxalatogermanate(IV) complex. The conversion into uniform manganese(IV) oxide particles was carried out from the manganese(II) carbonates as the starting materials. The reaction mechanisms of particle growth were examined on the uniform particles of hematite and manganese(II) carbonate by the chronomal analysis based on concentration changes of the metal ions remaining in the supernatant solutions during the reaction. The surface characterization of the metallic silver and copper particles was also carried out by X-ray photoelectron analysis." @default.
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• W2022373676 date "1997-05-01" @default.
• W2022373676 modified "2023-09-27" @default.
• W2022373676 title "Preparation of uniform metal (hydrous) oxide particles from the corresponding metal complex solutions" @default.
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• W2022373676 doi "https://doi.org/10.1016/s0300-9440(97)00016-7" @default.
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