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- W2022376546 abstract "ABSTRACT The extraction of Mo(VI) from its aqueous solutions into chloroform, in the presence of 3-hydroxy-2-naphthoic acid (HNA) and n-butyltriphenylphosphonium bromide (LBr), was investigated using 99-Mo tracer, and the composition of extracted species was studied. The yellow extracts from diluted sulfuric acid solutions (0.5 mol dm−3 H2SO4 to pH 5) contained ion-associates of phosphonium cations (L+) with oligonuclear anionic complexes of Mo(VI) and HNA. Whereas the mean nuclearity of the extracted species was increasing slightly from 2.6 to 3.0 with pH increasing from 1.2 to 4.1, the content of HNA in the species increased simultaneously more than three times. The highest values of molybdenum distribution ratio were found at pH 3.0-3.2, where as much as 95% of the total amount of molybdenum was extracted at c(HNA) = 14.6 mmol dm−3, c(HNA)/c(Mo) = 147, in the form of the species with a mean composition expressed by a ratio L+: Mo: HNA = 3.1:2.7:1.4. A comparison with previously studied ion-pair extraction of Mo(VI), in the presence of 2,3-dihydroxynaphthalene as a chelating reagent, is given." @default.
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- W2022376546 date "1994-06-01" @default.
- W2022376546 modified "2023-09-27" @default.
- W2022376546 title "ION-PAIR EXTRACTION OF MOLYBDENUM(VI) IN THE PRESENCE OF 3-HYDROXY-2-NAPHTHOIC ACID" @default.
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- W2022376546 doi "https://doi.org/10.1080/07366299408918226" @default.
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