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- W2022379752 abstract "The polarisation characteristics of Cd polycrystals and monocrystals, with (0001), (112̄0), and (101̄0) surfaces, were studied in 0.1 M NaCl + 0.04 M HCl (pH 1.3) and compared with thermodynamic equilibria. Anodic dissolution rates were independent of surface orientation, exhibiting Tafel slopes (ba) near 27 mV that were reasonably consistent with a rate controlled process based on mass transport of CdCl+ from the Outer Helmholtz Plane (OHP). Other processes are likely to have played a contributory role in the anodic behaviour, because crystallographic faceting accompanied dissolution. Cathodic evolution of hydrogen exhibited mixed rate control, with a cathodic Tafel slope (bc) near −81 mV. Hydrogen evolution appeared to be sensitive to surface orientation, with the (101̄0) surface showing the largest deviations in behaviour." @default.
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- W2022379752 date "1997-07-01" @default.
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- W2022379752 title "The behaviour of cadmium monocrystals and polycrystals in acid chloride solution" @default.
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