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- W2022381853 abstract "Abstract In order to assess the influence of tetrahedral sheet charge on the hydroxyl-stretching vibration in clay minerals, a series of synthetic Na-saponites, with increasing layer charge, was studied by infrared (IR) spectroscopy. When recorded after KBr dilution either in transmission or diffuse reflectance, the IR spectra exhibit a component at ~3710 cm -1 , the intensity of which increases linearly with increasing layer charge. When experiments are carried out without any dilution of the samples, this component is not observed, suggesting a Na + /K + exchange upon mixing of the sample with KBr. The spectra obtained for K-saponite confirm this exchange. This shows that the dilution procedure can lead to serious misinterpretations of IR spectra in the OH-stretching region." @default.
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- W2022381853 date "1999-09-01" @default.
- W2022381853 modified "2023-09-25" @default.
- W2022381853 title "Influence of KBr conditioning on the infrared hydroxyl-stretching region of saponites" @default.
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