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- W2022382879 abstract "A stereoselective method for synthesis of syn,syn- and syn,anti-1,3,5-triols based on a double allylboration-intramolecular hydrosilylation sequence has been developed. The 1,3-syn stereocontrol is achieved in the intramolecular hydrosilylation of monoprotected (Z)-1,5-syn-diols and (E)-1,5-anti-diols with 87:13 to 95:5 and 86:14 to 88:12 diastereomeric ratios, respectively, by using 0.5 mol % of Karstedt's catalyst in toluene." @default.
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- W2022382879 date "2009-06-09" @default.
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- W2022382879 title "Stereoselective Synthesis of <i>syn,syn</i>- and <i>syn</i>,<i>anti</i>-1,3,5-Triols via Intramolecular Hydrosilylation of Substituted Pent-3-en-1,5-diols" @default.
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- W2022382879 doi "https://doi.org/10.1021/ol9009877" @default.
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