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- W2022461026 abstract "Abstract Polycrystalline sample of Mn 3 [Fe(CN) 6 ] 2 ·xH 2 O was prepared by coprecipitation method. The coprecipitated powder was annealed in vacuum at different temperatures of 80, 100, 130, and 150 °C respectively. Changes of magnetic properties with different annealed temperatures were studied by Fourier‐transform infrared, X‐ray diffraction and magnetization measurements. The positive θ value of the Curie–Weiss temperature indicates the existence of a predominant ferromagnetic interaction over the anti‐ferromagnetic one in the compounds annealed at 80, 100, and 150 °C. The negative value of θ in Mn 3 [Fe(CN) 6 ] 2 ·xH 2 O annealed at 130 °C appears to be the coexistence of a strong anti‐ferromagnetic and a ferromagnetic interactions in the material. This is due to the existence of a relatively strong anti‐ferromagnetic contribution between the neighbouring Mn atoms bridged by the oxygen atom of the water molecule (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)" @default.
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- W2022461026 date "2011-08-03" @default.
- W2022461026 modified "2023-09-25" @default.
- W2022461026 title "Heat‐induced magnetic properties changes of Mn <sub>3</sub> [Fe(CN) <sub>6</sub> ] <sub>2</sub> ·xH <sub>2</sub> O" @default.
- W2022461026 doi "https://doi.org/10.1002/pssc.201084184" @default.
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