Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022470147> ?p ?o ?g. }
- W2022470147 endingPage "18414" @default.
- W2022470147 startingPage "18408" @default.
- W2022470147 abstract "The photophysical behavior of the transition metal complexes {[(bpy)2Ru]2(bphb)}(PF6)4, {[(tpy)(CN)Ru]2(bphb)}(PF6)2, and [(bpy)2Ru(bphb)Ru(tpy)(CN)](PF6)4 (bpy = 2,2‘-bipyridine, tpy = 2,2‘,6‘,2‘‘-terpyridine, bphb = 1,4-bis(2,2‘-bipyrid-4-yl)benzene) was investigated in acetonitrile solution and low-temperature glasses. Luminescence spectra, excitation spectra, and transient absorption decays of the three complexes serve to show that intramolecular electronic energy transfer from the MLCT excited state of the [(bpy)2Ru(bphb) chromophore to the MLCT state of the tpy-containing chromophore occurs in the unsymmetric bimetallic complex. Nearly complete energy transfer from the [(bpy)2Ru(bphb)] chromophore to the tpy-containing chromophore was observed even in 4:1 ethanol:methanol glasses at 20 K. A semiclassical exchange energy transfer mechanism was used to treat the available data; the Franck−Condon weighted density of states (FCWD) was obtained using parameters determined from fits of luminescence spectra. Given the FCWD at room temperature and the experimental rate constant, an electronic coupling matrix element of approximately 60 cm-1 was determined for this system." @default.
- W2022470147 created "2016-06-24" @default.
- W2022470147 creator A5003733437 @default.
- W2022470147 creator A5039063778 @default.
- W2022470147 creator A5067872666 @default.
- W2022470147 creator A5075918904 @default.
- W2022470147 creator A5078536482 @default.
- W2022470147 date "1996-01-01" @default.
- W2022470147 modified "2023-10-17" @default.
- W2022470147 title "Intramolecular Exchange Energy Transfer in a Bridged Bimetallic Transition Metal Complex: Calculation of Rate Constants Using Emission Spectral Fitting Parameters" @default.
- W2022470147 cites W1973803527 @default.
- W2022470147 cites W1974647194 @default.
- W2022470147 cites W1977929005 @default.
- W2022470147 cites W2002164208 @default.
- W2022470147 cites W2006354060 @default.
- W2022470147 cites W2016729529 @default.
- W2022470147 cites W2017328397 @default.
- W2022470147 cites W2020379489 @default.
- W2022470147 cites W2028723947 @default.
- W2022470147 cites W2028839593 @default.
- W2022470147 cites W2029452534 @default.
- W2022470147 cites W2031977250 @default.
- W2022470147 cites W2040142656 @default.
- W2022470147 cites W2041931011 @default.
- W2022470147 cites W2044345012 @default.
- W2022470147 cites W2047712774 @default.
- W2022470147 cites W2051460474 @default.
- W2022470147 cites W2059745748 @default.
- W2022470147 cites W2061582840 @default.
- W2022470147 cites W2061759819 @default.
- W2022470147 cites W2062224143 @default.
- W2022470147 cites W2065497508 @default.
- W2022470147 cites W2069273973 @default.
- W2022470147 cites W2074956690 @default.
- W2022470147 cites W2076707740 @default.
- W2022470147 cites W2078126271 @default.
- W2022470147 cites W2082542421 @default.
- W2022470147 cites W2086553013 @default.
- W2022470147 cites W2091639972 @default.
- W2022470147 cites W2091772955 @default.
- W2022470147 cites W2093277141 @default.
- W2022470147 cites W2145773666 @default.
- W2022470147 cites W2151003442 @default.
- W2022470147 cites W2154877434 @default.
- W2022470147 cites W2953279735 @default.
- W2022470147 cites W4210962031 @default.
- W2022470147 doi "https://doi.org/10.1021/jp961750r" @default.
- W2022470147 hasPublicationYear "1996" @default.
- W2022470147 type Work @default.
- W2022470147 sameAs 2022470147 @default.
- W2022470147 citedByCount "20" @default.
- W2022470147 countsByYear W20224701472013 @default.
- W2022470147 countsByYear W20224701472015 @default.
- W2022470147 countsByYear W20224701472018 @default.
- W2022470147 crossrefType "journal-article" @default.
- W2022470147 hasAuthorship W2022470147A5003733437 @default.
- W2022470147 hasAuthorship W2022470147A5039063778 @default.
- W2022470147 hasAuthorship W2022470147A5067872666 @default.
- W2022470147 hasAuthorship W2022470147A5075918904 @default.
- W2022470147 hasAuthorship W2022470147A5078536482 @default.
- W2022470147 hasConcept C115624301 @default.
- W2022470147 hasConcept C119824511 @default.
- W2022470147 hasConcept C121332964 @default.
- W2022470147 hasConcept C1276947 @default.
- W2022470147 hasConcept C147789679 @default.
- W2022470147 hasConcept C148869448 @default.
- W2022470147 hasConcept C148898269 @default.
- W2022470147 hasConcept C178790620 @default.
- W2022470147 hasConcept C181500209 @default.
- W2022470147 hasConcept C184779094 @default.
- W2022470147 hasConcept C185592680 @default.
- W2022470147 hasConcept C192468462 @default.
- W2022470147 hasConcept C2777463227 @default.
- W2022470147 hasConcept C2779336533 @default.
- W2022470147 hasConcept C43411465 @default.
- W2022470147 hasConcept C43617362 @default.
- W2022470147 hasConcept C4839761 @default.
- W2022470147 hasConcept C49040817 @default.
- W2022470147 hasConcept C544153396 @default.
- W2022470147 hasConcept C62520636 @default.
- W2022470147 hasConcept C71240020 @default.
- W2022470147 hasConcept C75079739 @default.
- W2022470147 hasConcept C75473681 @default.
- W2022470147 hasConcept C8010536 @default.
- W2022470147 hasConcept C93391505 @default.
- W2022470147 hasConcept C96141758 @default.
- W2022470147 hasConceptScore W2022470147C115624301 @default.
- W2022470147 hasConceptScore W2022470147C119824511 @default.
- W2022470147 hasConceptScore W2022470147C121332964 @default.
- W2022470147 hasConceptScore W2022470147C1276947 @default.
- W2022470147 hasConceptScore W2022470147C147789679 @default.
- W2022470147 hasConceptScore W2022470147C148869448 @default.
- W2022470147 hasConceptScore W2022470147C148898269 @default.
- W2022470147 hasConceptScore W2022470147C178790620 @default.
- W2022470147 hasConceptScore W2022470147C181500209 @default.
- W2022470147 hasConceptScore W2022470147C184779094 @default.
- W2022470147 hasConceptScore W2022470147C185592680 @default.
- W2022470147 hasConceptScore W2022470147C192468462 @default.