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- W2022476554 endingPage "88" @default.
- W2022476554 startingPage "77" @default.
- W2022476554 abstract "Binary mixtures of 1-alkanols and ethylbenzene, dimethylbenzenes or trimethylbenzenes have been studied in the framework of the DISQUAC model. The interaction parameters for the hydroxyl/aromatic contacts are reported. DISQUAC represents well a set of thermodynamic properties: vapor-liquid equilibria (VLE), liquid–liquid equilibria (LLE), molar excess enthalpies (HE) and the concentration–concentration structure factor (SCC(0)). The model predicts correctly HE of 1-alkanol + 1,4-dimethylbenzene + cyclohexane systems using binary parameters only, that is neglecting ternary interactions. The available database on HE and molar excess volume (VE) is examined in order to gain insight into the interactions present in the studied mixtures: (i) dipolar interactions are stronger in systems with benzene; (ii) interactions between unlike molecules decrease with the increase of the chain length of the 1-alkanol for solutions with a given aromatic hydrocarbon; (iii) self-association of 1-alkanols is more important in systems with alkylbenzenes than in those including benzene; (iv) benzene is a more active molecule than other aromatic compounds when breaking the alcohol structure." @default.
- W2022476554 created "2016-06-24" @default.
- W2022476554 creator A5007050426 @default.
- W2022476554 creator A5029774712 @default.
- W2022476554 creator A5043982232 @default.
- W2022476554 creator A5054647230 @default.
- W2022476554 creator A5067619915 @default.
- W2022476554 date "2007-03-01" @default.
- W2022476554 modified "2023-10-18" @default.
- W2022476554 title "Thermodynamics of 1-alkanol+aromatic compound mixtures. Systems with dimethylbenzene, ethylbenzene or trimethylbenzene" @default.
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