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- W2022479008 abstract "Abstract The existence has been proved, for the first time, in the LaLiFeO system of the phase (La1.75Li.25) (Fe.5Li.5)O4−x with tetragonal symmetry ( a o =3.765±0.001 A ; c o =12.918±0.01 A ; c o a o =3.43 ) and K2NiF4-type structure. This phase gives probably the first example of lithium distribution in both A and B sites of A2BO4-type mixed oxides. The high c o a o ratio suggests a strong elongation of FeO6 octahedra induced by a high spin Fe(IV) d4 configuration. The results of structural studies and of Mossbauer analysis, confirming the above conclusions, are reported." @default.
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- W2022479008 date "1985-04-01" @default.
- W2022479008 modified "2023-09-29" @default.
- W2022479008 title "New phase with K2NiF4 structure in the LaLiFeO system" @default.
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- W2022479008 doi "https://doi.org/10.1016/0025-5408(85)90006-6" @default.
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